Spin State Switching Triggered Light - Both Spacer Length and Parity Influence the Thermal and Light-Induced Properties of Spin Crossover Coordinat by Alina Absmeier

ISBN: 9783838102269

Published:

Paperback

160 pages


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Spin State Switching Triggered  by  Light - Both Spacer Length and Parity Influence the Thermal and Light-Induced Properties of Spin Crossover Coordinat by Alina Absmeier

Spin State Switching Triggered by Light - Both Spacer Length and Parity Influence the Thermal and Light-Induced Properties of Spin Crossover Coordinat by Alina Absmeier
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The influence of non-coordinating anions and spacer length of the ligand is analysed in extension of the systematic investigations into iron(II) spin cossover coordination polymers. Ditetrazole complexes of iron(II) perchlorate, tetrafluoroborate andMoreThe influence of non-coordinating anions and spacer length of the ligand is analysed in extension of the systematic investigations into iron(II) spin cossover coordination polymers.

Ditetrazole complexes of iron(II) perchlorate, tetrafluoroborate and hexafluorophosphate where the two tetrazole moieties are separated by alkylene spacers with different number of carbon atoms (n) are presented. Pronounced structural, optical, magnetic and magneto- optical changes are analysed and found in the comparison of the two series.The results allow a deeper insight in coherences between structural changes and electronic occupations, which can be detected as thermal, optical or magnetic spin transitions.



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